
Waste oil for biodiesel synthesis
Alkoxides for Biodiesel
Among alternative energy sources, biodiesel, made from a mix of diverse resources such as recycled cooking oil is a bridging technology on the road to sustainable mobility. We have accompanied the development of biodiesel since the start of commercial production. In addition to traditional feedstocks, we focus on second-generation raw materials. These include above all Jatropha curcas or algae, whose harvest does not compete with food cultivation.
In many countries, blending biodiesel with fossil diesel is mandatory. The green fuel is biodegradable, non-toxic, poses no threat to drinking water and can be used in existing diesel engines. As a result, fewer greenhouse gases and soot are emitted, which significantly improves the energy balance. In addition, biodiesel is not a hazardous material, which makes it easier to transport, store and handle. Biodiesel is characterized by excellent lubricity and is also gentle on the vehicle engine.
The key benefits of biodiesel at a glance
- Reduced CO2 emissions up to 67%
- Reduces greenhouse gases by up to 86% over the entire life cycle
- Lower soot amounts in exhaust gas
- Biodiesel is not a hazardous material
- Biodiesel is biodegradable
- Less energy requirement and lower costs through transesterification
Our alkoxide product portfolio is tailored to the special requirements of the manufacture and use of modern, high-tech fuel. We offer:
- Alkoxides as catalysts for efficient transesterification
- Anti-foaming agents for effective use of biodiesel blends
- Flow improvers for outstanding low-temperature properties in all regions in all seasons
- Special polyamide 12 for special, durable automotive components
- Process engineering consulting
FROM NATIVE OIL TO HIGH-TECH Biodiesel
TRANSESTERIFICATION
Due to their molecular structure, vegetable oils are not suitable for use as fuel in conventional diesel engines. Vegetable and animal fats consist of triglycerides, that is, the combination of the trivalent alcohol glycerol with three fatty acids. If the glycerol is replaced with methanol, the viscous vegetable oil is transformed into a fuel with excellent flow characteristics: biodiesel.
And all it takes is a simple chemical reaction called transesterification, which involves mixing methanol with a small quantity of an alkaline catalyst which provides cost savings and performance and selectivity that provides a good biodiesel yield. The most effective catalysts are the metal alkoxide catalyst sodium methylate in the form of a 30% solution in methanol (NM 30) and potassium methylate in the form of a 32% solution in methanol (KM 32), both from Evonik.
In addition to the main product, biodiesel, transesterification also yields glycerol as a valuable byproduct.

Our Catalysts
Product |
Application / Requirements of Raw Materials |
Solution |
|
30% |
|
|
32% |
Both catalysts can be used in anhydrous production processes in a closed circuit directly from the storage tank without any additional intermediary steps. This reduces the risks associated with handling alkoxides to an absolute minimum.
Analytics
For many years our analytical labs have been working on the alkoxide-catalyzed transesterification process and the quality characteristics of the target product biodiesel. In addition to production-related analysis, we also examine your raw materials and end products. Based on the results of our analytical tests, you benefit from our consulting competency, for example, through avoiding yield losses or irregularities in the production process. Please contact us for further information!
BIODIESEL END-PRODUCT TEST IN ACCORDANCE WITH EN 14214
Parameter |
Unit |
Test Procedure |
Ester content |
% (m/m) |
EN 14103 |
Linolenic acid ME content |
% (m/m) |
EN 14103 |
Water content |
mg/kg |
EN ISO 12937 |
Total contamination |
mg/kg |
EN 12662 |
Oxidation stability, 110 °C |
h |
EN 14112 |
Acid value |
mg KOH/g |
EN 14104 |
Iodine value |
g Iod/100 g |
EN 14111 |
Methanol content |
% (m/m) |
EN 14110 |
Monoglyceride content |
% (m/m) |
EN 14105 |
Diglyceride content |
% (m/m) |
EN 14105 |
Triglyceride content |
% (m/m) |
EN 14105 |
Free glycerol content |
% (m/m) |
EN 14105 |
Total glycerol content |
% (m/m) |
EN 14105 |
Alkali metal content (Na+K) |
mg/kg |
EN 14108 |
Phosphorus content |
mg/kg |
EN 14107 |
Density (15 °C) |
kg/m³ |
EN ISO 3675 |
Viscosity (40 °C) |
mm²/s |
EN ISO 3104 |
Flash point |
°C |
ISO/CD 3679 |
Sulphur content |
mg/kg |
DIN EN 20884 |
Sulphated ash content |
% (m/m) |
ISO 3987 |
FAME content with more than 3 double bonds |
% (m/m) |
EN 14103 |
CFPP |
°C |
DIN EN 116 |
Analytics of raw materials and byproducts
Raw Materials / Byproducts |
Crude Oil |
Fatty Acid Content |
|
|
Phosphatide content |
|
Methanol |
Water content |
Byproducts |
Glycerin |
Content (Titr.) |
|
|
Soap content |
|
Soapstock |
Ester content |
Waste |
Wastewater |
CSB |
Our engineering optimizes your processes
Know-how for greater plant efficiency
Our work focuses on process optimization to provide economic benefits to the biodiesel industry. The goal is always to make the plants more cost-efficient and more effective. The topics range from the use of new oils and the optimization of individual reaction and separation stages in existing biodiesel procedures to how capacity expansions of 20 to 30 percent can be achieved cost-effectively through elimination of bottlenecks in the existing plants.
In these projects, we support you with interdisciplinary teams from development of the solution through preselection and testing in our labs or technical centers and finally, to successful large-scale implementation.

We advise you from project management to commissioning
International experience
The core competency in the engineering sector is in the planning and construction of production plants - domestically and internationally. In the biodiesel area, we focus on optimization measures such as the elimination of bottlenecks. Our range of services covers:
- Project management including quality, cost, and schedule controlling
- Planning services such as potential analyses, basic and detailed planning
- Specialist services from apparatus technology to production logistics
- Construction and assembly management
- And finally, support with commissioning and training of your employees
These services are provided exclusively by competent and experienced engineers, the key reason to ensure that the project goals can be achieved to your fullest satisfaction.